2017 - 20th Annual Steven Galovich Memorial Student Symposium

Presentation Title

Ionothermal Synthesis and Characterization of Two New Iron Thiophosphates

Student Presenter(s) and Advisor

Sae Rom Kang, Lake Forest CollegeFollow

Location

Hotchkiss Hall Lobby

Abstract

Two new iron thiophosphate anions, [Fe(P2S8)2]2– and [FeP7S16], were synthesized in two different ionic liquids. These new anions have different iron to phosphorous to sulfur ratios than any known compounds with these same elements. The [Fe(P2S8)2]2– anion is very similar to a nickel-containing anion previously prepared in our laboratory, but the [FeP7S16] anion is entirely new and not completely resolved. Although it is unlikely these compounds have commercial application, the implications of this basic research to renewable energy will be discussed.

Presentation Type

Poster

Start Date

4-11-2017 2:30 PM

End Date

4-11-2017 3:45 PM

Panel

Posters

Panel Moderator

Jason A. Cody

Field of Study for Presentation

Chemistry

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Apr 11th, 2:30 PM Apr 11th, 3:45 PM

Ionothermal Synthesis and Characterization of Two New Iron Thiophosphates

Hotchkiss Hall Lobby

Two new iron thiophosphate anions, [Fe(P2S8)2]2– and [FeP7S16], were synthesized in two different ionic liquids. These new anions have different iron to phosphorous to sulfur ratios than any known compounds with these same elements. The [Fe(P2S8)2]2– anion is very similar to a nickel-containing anion previously prepared in our laboratory, but the [FeP7S16] anion is entirely new and not completely resolved. Although it is unlikely these compounds have commercial application, the implications of this basic research to renewable energy will be discussed.